1-Octene → Octane

HRID 567658

反応式

HRID 567658 の反応式
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>C1CCCCC1.CCCCCCC.[CH-]1[C-]=[C-][C-]=[C-]1.[CH-]1[C-]=[C-][C-]=[C-]1.Cl[Ti]Cl>[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH3:1][CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

6

反応物 1

HCID 81251-Octene

生成物 2

HCID 356OctaneHCID 8126Oct-2-ene

試薬・触媒・溶媒 3

HCID 416358Bis(cyclopentadienyl)titanium(IV) chloride触媒HCID 8078Cyclohexane溶媒2 回HCID 8900Heptane溶媒

実験手順

0.12 mmoles of bis-(η5-cyclopentadienyl)titanium dichloride (Cp2TiCl2; Aldrich commercial product), 20 ml of anhydrous cyclohexane, 0.03 ml of a solution of n-dibutylglima 0.45 M in anhydrous cyclohexane and 0.54 ml of 1 molar Mg(butyl)2 in n-heptane (atomic ratio Mg/Ti=4.5), are charged into a tailed test-tube equipped with a magnetic stirrer, in an atmosphere of argon. The mixture is left under stirring for 20 hours at room temperature. 18.8 ml of 1-octene (distilled and maintained on molecular sieves) are added. At this point the solution is siphoned in an autoclave previously maintained under argon and the same procedure is carried out as described in example 1 above. At the end it is cooled to room temperature. About 14 ml of octane and 4 ml of 2-octene are obtained by distillation (GC, mass GC and NMR analyses). The results and process conditions are summarized in table 1 below.

後処理

  1. customequipped with a magnetic stirrer, in an atmosphere of argon
  2. waitThe mixture is left
  3. temperaturepreviously maintained under argon
  4. temperatureAt the end it is cooled to room temperature

出典と根拠

ORDレコード
ord-eeb13e21c0b84dd1bbb2834d05d724ac
出典データセット
uspto-grants-2001_01
特許番号
US06180553B2

関連ノート

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