9-Phenylanthracene → 9-Bromo-10-phenyl-anthracene

HRID 571588

反応式

HRID 571588 の反応式
[C:1]1([C:7]2[C:8]3[C:13]([CH:14]=[C:15]4[C:20]=2[CH:19]=[CH:18][CH:17]=[CH:16]4)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:21]C1CC(=O)NC1=O>CN(C)C=O>[Br:21][C:14]1[C:15]2[C:20]([C:7]([C:1]3[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=3)=[C:8]3[C:13]=1[CH:12]=[CH:11][CH:10]=[CH:9]3)=[CH:19][CH:18]=[CH:17][CH:16]=2

参加物

4

反応物 2

HCID 117669-PhenylanthraceneHCID 38309Bromosuccinimide

生成物 1

HCID 41558369-Bromo-10-phenyl-anthracene収率 89.3%

試薬・触媒・溶媒 1

HCID 6228Dimethylformamide溶媒

実験手順

An amount of 13.65 (53.7 mmol) of 9-phenylanthracene was dissolved in 100 ml of N,N dimethylformamide. An amount of 10.5 g (59 mmol) of N bromosuccinimide was added and allowed to react for six hours. Then, distilled water was added to stop the reaction and the deposit was filtered. The recovered deposit was purified by column chromatography to obtain 15.97 g (48 mmol) of 9-bromo-10-phenylanthracene. The yield was 89.3%.

後処理

  1. customto react for six hours
  2. distillationThen, distilled water
  3. additionwas added
  4. customthe reaction
  5. filtrationthe deposit was filtered
  6. customThe recovered deposit was purified by column chromatography

出典と根拠

ORDレコード
ord-56710cff061b48a6b28fa13d1d514b10
出典データセット
uspto-grants-2015_05
特許番号
US09028976B2

関連ノート

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