3,3-Diethoxy-1-propanol → 3,3-Diethoxy-1-propanol

HRID 582798ノート

反応式

HRID 582798 の反応式
[CH2:1]([O:3][CH:4]([O:8][CH2:9][CH3:10])[CH2:5][CH2:6][OH:7])[CH3:2].C1C2C(=CC=CC=2)C=CC=1.[K:21]>O1CCCC1>[K:21].[CH2:1]([O:3][CH:4]([O:8][CH2:9][CH3:10])[CH2:5][CH2:6][OH:7])[CH3:2]

参加物

5

反応物 2

HCID 1401353,3-Diethoxy-1-propanolHCID 66602812Naphthalene potassium

生成物 2

HCID 1401353,3-Diethoxy-1-propanolHCID 5462222Potassium

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒3 回

実験手順

A reactor was charged with 30 ml of THF, 0.13 g of 3, 3-diethoxypropanol and 2 ml solution of potassium naphthalene dissolved in tetrahydrofuran in a concentration of 0.5 mol/L-tetrahydrofuran, and the resulting mixture was stirred for three minutes in an argon atmosphere, and, thus, there was formed a potassium derivative (potassium 3, 3-diethoxypropanoxide) of 3, 3-diethoxypropanol.

出典と根拠

ORDレコード
ord-04bb0291bcd64345a483338c57e0abaa
出典データセット
uspto-grants-1999_07
特許番号
US05925720

反応ノート

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