Azobisisobutyronitrile → tert-Butyl methacrylate

HRID 582950

反応式

HRID 582950 の反応式
C(O[C:7]1[CH:16]=[CH:15][C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=1)(=O)C(C)=C.[C:17]([O:22][C:23]([CH3:26])([CH3:25])[CH3:24])(=[O:21])[C:18]([CH3:20])=[CH2:19].CC(N=NC(C#N)(C)C)(C#N)C>C1(C)C=CC=CC=1>[C:17]([O:22][C:10]1[C:9]2[C:14](=[CH:15][CH:16]=[CH:7][CH:8]=2)[CH:13]=[CH:12][CH:11]=1)(=[O:21])[C:18]([CH3:20])=[CH2:19].[C:17]([O:22][C:23]([CH3:26])([CH3:25])[CH3:24])(=[O:21])[C:18]([CH3:20])=[CH2:19]

参加物

6

反応物 3

HCID 6547AzobisisobutyronitrileHCID 11448tert-Butyl methacrylateHCID 826542-Naphthyl methacrylate

生成物 2

HCID 11448tert-Butyl methacrylateHCID 4064248Naphthyl methacrylate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
70 °C

実験手順

0.3 mol of 2-naphthyl methacrylate and 0.7 mol of tert-butyl methacrylate were mixed with 200 g of toluene, and 2 g of azoisobutylonitrile (AIBN) was added thereto. The mixed system was heated at a temperature of 70° C. for 8 hours and then purified by dropping it into acetone-methanol solvent, to obtain a copolymer of naphthyl methacrylate and tert-butyl methacrylate (Resin A).

後処理

  1. additionwas added
  2. custompurified

出典と根拠

ORDレコード
ord-c7bbf83b99be495ab8fe0686ac13772c
出典データセット
uspto-grants-1999_07
特許番号
US05928841

関連ノート

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