反応式
C(C1C=CC(C(C)C(O)=O)=CC=1)C(C)C.C(NC(=CC1C=CC=CC=1)C(O)=O)(=O)C.S(C1C=CC(CCC[C:44]2[CH:49]=[CH:48][C:47]([P:50]([C:110]3[CH:115]=[CH:114][C:113](CCCC4C=CC(S([O-])(=O)=O)=CC=4)=[CH:112][CH:111]=3)[C:51]3[CH:60]=[CH:59][C:58]4[C:53](=[CH:54][CH:55]=[CH:56][CH:57]=4)[C:52]=3[C:61]3[C:70]4[C:65](=[CH:66][CH:67]=[CH:68][CH:69]=4)[CH:64]=[CH:63][C:62]=3[P:71]([C:91]3[CH:96]=[CH:95][C:94](CCCC4C=CC(S([O-])(=O)=O)=CC=4)=[CH:93][CH:92]=3)[C:72]3[CH:77]=[CH:76][C:75](CCCC4C=CC(S([O-])(=O)=O)=CC=4)=[CH:74][CH:73]=3)=[CH:46][CH:45]=2)=CC=1)([O-])(=O)=O>>[CH:113]1[CH:112]=[CH:111][C:110]([P:50]([C:51]2[CH:60]=[CH:59][C:58]3[C:53](=[CH:54][CH:55]=[CH:56][CH:57]=3)[C:52]=2[C:61]2[C:70]3[C:65](=[CH:66][CH:67]=[CH:68][CH:69]=3)[CH:64]=[CH:63][C:62]=2[P:71]([C:72]2[CH:77]=[CH:76][CH:75]=[CH:74][CH:73]=2)[C:91]2[CH:96]=[CH:95][CH:94]=[CH:93][CH:92]=2)[C:47]2[CH:46]=[CH:45][CH:44]=[CH:49][CH:48]=2)=[CH:115][CH:114]=1参加物
4
実験手順
According to Example 6, 2-(4-isobutylphenyl) propanoic acid and the methyl ester of acetylaminocinnamic acid were asymmetrically hydrogenated with the Rh- or Ru complexes of (R)-(+)-BINAP-C3 -TS (Table 4).
出典と根拠
- ORDレコード
- ord-d969d650eda74cc1b8497eaf1c7c5c94
- 出典データセット
- uspto-grants-1999_07
- 特許番号
- US05929273
関連ノート
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