(3-Bromo-4-methylphenyl)methanol → 3-Bromo-4-methylbenzaldehyde
反応式
[Br:1][C:2]1[CH:3]=[C:4]([CH2:9][OH:10])[CH:5]=[CH:6][C:7]=1[CH3:8]>ClCCl.[O-2].[Mn+2]>[Br:1][C:2]1[CH:3]=[C:4]([CH:5]=[CH:6][C:7]=1[CH3:8])[CH:9]=[O:10]参加物
4
実験手順
14.4 g (72 mmol) of (3-bromo-4-methylphenyl)methanol are placed in 200 ml of dichloromethane in a round-bottomed flask. 62.6 g (72 mmol) of manganese oxide are added and the medium is stirred at room temperature overnight. The mixture is filtered through Celite and the solvent is evaporated off. 11.8 g (85%) of the expected product are obtained in the form of an oil.
後処理
- filtrationThe mixture is filtered through Celite
- customthe solvent is evaporated off
出典と根拠
- ORDレコード
- ord-20172710c0904141ac8730fb33bb8ee2
- 出典データセット
- uspto-grants-2005_08
- 特許番号
- US06924400B2
反応ノート
読み込み中…