Triethoxychlorosilane → Acryltriethoxysilane

HRID 584335

反応式

HRID 584335 の反応式
[C:1]([O-:5])(=O)[CH:2]=[CH2:3].[Na+].Cl[Si:8]([O:15][CH2:16][CH3:17])([O:12][CH2:13][CH3:14])[O:9][CH2:10][CH3:11]>C1COCC1>[C:1]([Si:8]([O:15][CH2:16][CH3:17])([O:12][CH2:13][CH3:14])[O:9][CH2:10][CH3:11])([CH:2]=[CH2:3])=[O:5]

参加物

4

反応物 2

HCID 78398TriethoxychlorosilaneHCID 4068533Sodium acrylate

生成物 1

HCID 21864273Acryltriethoxysilane

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒2 回

反応条件

温度
-70 °C

実験手順

6.123 g (0.0651 mol) sodium acrylate is dissolved to 25 mL THF and cooled to −70° C. 12.8 mL (0.0651 mol, 12.938 g) chlorotriethoxysilane in THF (15 mL) is added dropwise to reaction solution. The solution is stirred for over night allowing it to warm up to room temperature. NaCl is removed by filtration and solution evaporated to dryness to result clear liquid, acryltriethoxysilane.

後処理

  1. temperatureto warm up to room temperature
  2. customNaCl is removed by filtration and solution
  3. customevaporated to dryness

出典と根拠

ORDレコード
ord-eaebcd9269f74587b4e7065e698a739f
出典データセット
uspto-grants-2005_08
特許番号
US06924384B2

関連ノート

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