6-Benzoylbenzoselenazolinone → Bis(2-amino-5-benzoylphenyl) diselenide

HRID 5920ノート

反応式

HRID 5920 の反応式
[C:1]([C:9]1[CH:18]=[CH:17][C:12]2[N:13]=C[Se:15](=O)[C:11]=2[CH:10]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>[OH-].[Na+]>[NH2:13][C:12]1[CH:17]=[CH:18][C:9]([C:1](=[O:8])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)=[CH:10][C:11]=1[Se:15][Se:15][C:11]1[CH:10]=[C:9]([C:1](=[O:8])[C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)[CH:18]=[CH:17][C:12]=1[NH2:13]

参加物

3

反応物 1

HCID 1317181726-Benzoylbenzoselenazolinone

生成物 1

HCID 10370310Bis(2-amino-5-benzoylphenyl) diselenide

試薬・触媒・溶媒 1

HCID 14798Sodium Hydroxide溶媒

実験手順

1.5 g (0.005 mol) of 6-benzoylbenzoselenazolinone are introduced together with 20 cm3 of 10% sodium hydroxide into a ground-necked flask. The mixture is heated to reflux with stirring for two hours. After cooling, the reaction medium is neutralized. The precipitate is drained, washed with water and dried and the product is recrystallized in toluene.

後処理

  1. temperatureThe mixture is heated
  2. temperatureto reflux
  3. temperatureAfter cooling
  4. washwashed with water
  5. customdried
  6. customthe product is recrystallized in toluene

出典と根拠

ORDレコード
ord-20f53bdf122d4c0eb79fea6119fe9f55
出典データセット
uspto-grants-1993_09
特許番号
US05246951

反応ノート

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