Hydrochloric Acid → N1,4,5-Trimethylbenzene-1,2-diamine

HRID 59279ノート

反応式

HRID 59279 の反応式
[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([CH3:9])[C:6]([CH3:10])=[CH:5][C:4]=1[N+:11]([O-])=O.Cl>[Fe].CO>[CH3:1][NH:2][C:3]1[C:4]([NH2:11])=[CH:5][C:6]([CH3:10])=[C:7]([CH3:9])[CH:8]=1

参加物

5

反応物 2

HCID 313Hydrochloric AcidHCID 601943HCID 601943、化合物

生成物 1

HCID 591611N1,4,5-Trimethylbenzene-1,2-diamine収率 42%

試薬・触媒・溶媒 2

HCID 23925Iron触媒HCID 887Methanol溶媒

実験手順

The title compound was prepared according to the procedure described in step-2 of Intermediate-28 by using N1,4,5-trimethyl-2-nitroaniline (0.350 g, 1.9 mmol), methanol (20 mL), Iron powder (1.75 g, 9.75 mmol), conc. HCl (5 mL) to afford 0.120 g of desired product.

後処理

  1. customThe title compound was prepared

出典と根拠

ORDレコード
ord-b7238f02a1d24982b67171d3245be330
出典データセット
uspto-grants-2016_09
特許番号
US09439890B2

反応ノート

読み込み中…