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Dimethyldithiocarbamic acid, dimethylamine → 3,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethyldithiocarbamic acid, dimethylamine | HCID 11728 | — |
| 反応物 | 3,4-Dimethoxy-beta-nitrostyrene | HCID 222093 | — |
| 溶媒 | Carbon Disulfide | HCID 6348 | — |
| 生成物 | 3,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate | HCID 21324596 | — |
反応手順
As in Example 17, reaction of 3,4-dimethoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-dimethoxy-α-(nitromethyl)-benzyl dimethyldithiocarbamate melting at 108° C.-110° C. after recrystallization without heating from acetone-methanol solution.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04011230 |
| 出典データセット | uspto-grants-1977_03 |
| ORD ID | ord-3988e83e65054981a44da5047bbc4b0f |
| 出典メモ | uspto-grants-1977_03 |