Dimethyldithiocarbamic acid, dimethylamine → 3,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

HRID 596505Notes

Reaction equation

HRID 596505 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:11]=[CH:12][C:13]=1[O:14][CH3:15])[CH:6]=[CH:7][N+:8]([O-:10])=[O:9].[CH3:16][N:17]([CH3:21])[C:18](=[S:20])[S-:19].C[NH2+]C>C(=S)=S>[CH3:16][N:17]([CH3:21])[C:18](=[S:19])[S:20][CH:6]([CH2:7][N+:8]([O-:10])=[O:9])[C:5]1[CH:11]=[CH:12][C:13]([O:14][CH3:15])=[C:3]([O:2][CH3:1])[CH:4]=1

Participants

4

Reactant 2

HCID 11728Dimethyldithiocarbamic acid, dimethylamineHCID 2220933,4-Dimethoxy-beta-nitrostyrene

Product 1

HCID 213245963,4-Dimethoxy-alpha-(nitromethyl)benzyl dimethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

As in Example 17, reaction of 3,4-dimethoxy-β-nitrostyrene with dimethylammonium dimethyldithiocarbamate in the presence of carbon disulfide gave 3,4-dimethoxy-α-(nitromethyl)-benzyl dimethyldithiocarbamate melting at 108° C.-110° C. after recrystallization without heating from acetone-methanol solution.

Sources & evidence

ORD record
ord-3988e83e65054981a44da5047bbc4b0f
Source dataset
uspto-grants-1977_03
Patent number
US04011230

Reaction notes

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