4-(2-Phenoxyethoxy)-2-nitroaniline → 1,2-Diamino-4-(2phenoxyethoxy)benzene
反応式
[O:1]([CH2:8][CH2:9][O:10][C:11]1[CH:17]=[CH:16][C:14]([NH2:15])=[C:13]([N+:18]([O-])=O)[CH:12]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[H][H]>[Pd].CO>[NH2:15][C:14]1[CH:16]=[CH:17][C:11]([O:10][CH2:9][CH2:8][O:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)=[CH:12][C:13]=1[NH2:18]参加物
5
実験手順
A mixture of 1.8 g. of 4-(2-phenoxyethoxy)-2-nitroaniline and 0.3 g. of 5% of palladium-on-charcoal catalyst in 200 ml. of methanol is hydrogenated under ambient conditions. After the uptake of hydrogen is complete, the mixture is filtered and 1,2-diamino-4-(2phenoxyethoxy)benzene is isolated from the filtrate by evaporation.
後処理
- additionA mixture of 1.8 g
- filtrationthe mixture is filtered
出典と根拠
- ORDレコード
- ord-016772973b01437cba4c35dbc361dba4
- 出典データセット
- uspto-grants-1977_03
- 特許番号
- US04011320
反応ノート
読み込み中…