Isobutylene → HCID 21446503、化合物

HRID 597100

反応式

HRID 597100 の反応式
[OH:1][CH:2]1[CH2:11][CH2:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH2:3]1.[CH3:12][C:13](=[CH2:15])[CH3:14]>[Hg](Cl)Cl.[Al]>[C:13]([CH:3]1[C:4]2[C:9](=[CH:8][CH:7]=[CH:6][CH:5]=2)[CH2:10][CH2:11][CH:2]1[OH:1])([CH3:15])([CH3:14])[CH3:12]

参加物

5

反応物 2

HCID 8255IsobutyleneHCID 107471,2,3,4-Tetrahydro-2-naphthalenol

生成物 1

HCID 21446503HCID 21446503、化合物収率 69.3%

試薬・触媒・溶媒 2

HCID 24085Mercuric Chloride触媒HCID 5359268Aluminum触媒

反応条件

温度
100 °C

実験手順

In an autoclave 222 g of 2-hydroxytetraline, 2.5 g of aluminium grit and 0.2 g of mercury(II) chloride are heated at 180° C for 1 h. After cooling 85 g of isobutylene are added and the mixture is stirred at 100° C for 3 h. In order to eliminate the catalyst the reaction product is washed with diluted hydrochloric acid. A subsequent distillation yields 212 g of 1-t-butyl-2-hydroxytetraline. Boiling point (13 mm Hg): 171° C. Melting point: 104° C.

後処理

  1. additionare added
  2. washis washed with diluted hydrochloric acid
  3. distillationA subsequent distillation

出典と根拠

ORDレコード
ord-33ca7b4a62c34afd98049e27b4c19f52
出典データセット
uspto-grants-1977_03
特許番号
US04013473

関連ノート

読み込み中…