N,N,N'-Trimethyl-N'-(5-nitro-benzooxazol-2-yl)-ethane-1,2-diamine → N2-(2-Dimethylamino-ethyl)-N2-methyl-benzooxazole-2,5-diamine
反応式
[CH3:1][N:2]([CH3:19])[CH2:3][CH2:4][N:5]([CH3:18])[C:6]1[O:7][C:8]2[CH:14]=[CH:13][C:12]([N+:15]([O-])=O)=[CH:11][C:9]=2[N:10]=1>[Fe].C(O)(=O)C>[CH3:1][N:2]([CH3:19])[CH2:3][CH2:4][N:5]([CH3:18])[C:6]1[O:7][C:8]2[CH:14]=[CH:13][C:12]([NH2:15])=[CH:11][C:9]=2[N:10]=1参加物
4
実験手順
The title compound was prepared according to the procedure described in General Method B using N,N,N′-Trimethyl-N′-(5-nitro-benzooxazol-2-yl)-ethane-1,2-diamine (4.131 g, 15.63 mmol), acetic acid (50 mL), and Fe (8.72 g, 78.15 mmol), stirring for 3 h: (3.57 g, 98%): mass spectrum (m/e): 265.3 (M+1).
出典と根拠
- ORDレコード
- ord-7526b8b2a69742b185fcbefdb0e51dbc
- 出典データセット
- uspto-grants-2011_03
- 特許番号
- US07902356B2
反応ノート
読み込み中…