2,2'-Dihydroxy-4-methoxybenzophenone → Drometrizole

HRID 602228

反応式

HRID 602228 の反応式
[OH:1][C:2]1[C:7](C(C)(C)C)=[CH:6][C:5]([C:12](C)(C)C)=[CH:4][C:3]=1[N:16]1[N:20]=[C:19]2[CH:21]=[CH:22][CH:23]=[CH:24][C:18]2=[N:17]1.OC1C(C(C)(C)C)=CC(C)=CC=1N1N=C2C=CC=CC2=N1.OC1C(C(C)(C)C)=CC(C(C)(C)C)=CC=1N1N=C2C=CC(Cl)=CC2=N1.OC1C(C(C)(C)C)=CC(C)=CC=1N1N=C2C=CC(Cl)=CC2=N1.OC1C=C(O)C=CC=1C(C1C=CC=CC=1)=O.OC1C=C(OC)C=CC=1C(C1C=CC=CC=1O)=O.OC1C=C(OC)C(S(O)(=O)=O)=CC=1C(C1C=CC=CC=1)=O.C(SC1N=C(SCCCCCCCC)N=C(NC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)N=1)CCCCCCC.OC1C(C(CC)(C)C)=CC(C(CC)(C)C)=CC=1N1N=C2C=CC(Cl)=CC2=N1.C(C1C(O)=C(C(C)(C)C)C=C(C)C=1)(C)(C)C.C(C1C=C(CCC(OCCOCCOCCOC(=O)CCC2C=C(C)C(O)=C(C(C)(C)C)C=2)=O)C=C(C)C=1O)(C)(C)C.C(C1C=C(CCC(OCCCCCCOC(=O)CCC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=O)C=C(C(C)(C)C)C=1O)(C)(C)C.CC1C(CC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=C(C)C(CC2C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=2)=C(C)C=1CC1C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=1.CC(C1C(O)=C(C(C)(C)C)C=C(CN2C(=O)N(CC3C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=3)C(=O)N(CC3C=C(C(C)(C)C)C(O)=C(C(C)(C)C)C=3)C2=O)C=1)(C)C>>[OH:1][C:2]1[CH:7]=[CH:6][C:5]([CH3:12])=[CH:4][C:3]=1[N:16]1[N:20]=[C:19]2[CH:21]=[CH:22][CH:23]=[CH:24][C:18]2=[N:17]1

参加物

15

反応物 14

HCID 85692,2'-Dihydroxy-4-methoxybenzophenoneHCID 85722,4-DihydroxybenzophenoneHCID 19988SulisobenzoneHCID 314042,6-Di-tert-butyl-4-methylphenolHCID 62531TinuvinHCID 64870Hexamethylene glycol bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate)HCID 70431Phenol, 4-((4,6-bis(octylthio)-1,3,5-triazin-2-yl)amino)-2,6-bis(1,1-dimethylethyl)-2 回HCID 743701,3,5-Trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzeneHCID 774552-(2'-Hydroxy-3'5-di-tert-butylphenyl) benzotriazoleHCID 774702,4-Di-tert-butyl-6-(5-chloro-2H-benzotriazol-2-yl)phenol2 回HCID 91620Antioxidant 245HCID 93115Tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurateHCID 155678932-(2'-Hydroxy-3'-tert-butyl-5'-methyphenyl)benzotriazoleHCID 21954258HCID 21954258、化合物

生成物 1

HCID 17113Drometrizole

実験手順

2-(2′-hydroxy-3′,5′-di-tert-butylphenyl) benzotriazol; 2-(2′-hydroxy-3′-tert-butyl-5′-methylphenyl) benzotriazol; 2-(2′-hydroxy-3′,5′-di-tert-butylphenyl)-5-chlorobenzotriazol; 2-(2′-hydroxy-3′-(3″,4″,5″,6″-tetrahydrophthalimidomethyl)-5′-methylphenyl) benzotriazol; 2,2-methylene bis (4-(1,1,3,3-tetramethylbutyl)-6-(2H-benzotriazol-2-yl) phenol); 2-(2′-hydroxy-3′-tert-butyl-5′-methylphenyl)-5-chlorobenzotriazol; 2,4-dihydroxybenzophenone; 2,2′-dihydroxy-4-methoxybenzophenone; 2-hydroxy-4-methoxy-5-sulfobenzophenone; bis(2-methoxy-4-hydroxy-5-benzoylphenylmethane); (2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine; 2-(2′-hydroxy-3′,5′-di-tert-butylphenyl)-5-chlorobenzotriazol; 2(2′-hydroxy-3′,5′-di-tert-amylphenyl)-5-chlorobenzotriazol; 2,6-di-tert-butyl-p-cresol; pentaerythrityl-tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]; triethyleneglycol-bis[3-(3-tert-butyl-5-methyl-4-hydroxyphenyl) propionate]; 1,6-hexanediol-bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]; 2,4-bis-(n-octylthio)-6-(4-hydroxy-3,5-di-tert-butylanilino)-1,3,5-triazine; 2,2-thio-diethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]; octadecyl-3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate; N,N′-hexamethylene bis(3,5-di-tert-butyl-4-hydroxy-hydrocinnamide); 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl) benzene; tris-(3,5-di-tert-butyl-4-hydroxybenzyl)-isocyanurate and the like.

出典と根拠

ORDレコード
ord-c3a65d0264cb46b8b1a4702d6fdcc804
出典データセット
uspto-grants-2011_03
特許番号
US07905944B2

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