3'-Aminoacetophenone → N,N'-bis(3-acetylphenyl)pentanediamide

HRID 613822

反応式

HRID 613822 の反応式
C([C:4]1[CH:5]=[C:6]([CH:8]=[C:9]([C:11](=[O:13])[CH3:12])[CH:10]=1)[NH2:7])(=O)C.C(C1C=C(N[C:27](=O)[CH2:28][CH2:29][C:30]([NH:32][C:33]2[CH:38]=[C:37]([C:39](=[O:41])[CH3:40])[CH:36]=[C:35](C(=O)C)[CH:34]=2)=[O:31])C=C(C(=O)C)C=1)(=O)C.[C:46](C1C=C(NC(=O)CCCCC(NC2C=C(C(=O)C)C=C(C(=O)C)C=2)=O)C=C(C(=O)C)C=1)(=[O:48])C.C(C1C=C(NC(=O)CCCCCC(NC2C=C(C(=O)C)C=C(C(=O)C)C=2)=O)C=C(C(=O)C)C=1)(=O)C.C(C1C=C(NC(=O)CCCCCCC(NC2C=C(C(=O)C)C=C(C(=O)C)C=2)=O)C=C(C(=O)C)C=1)(=O)C.C(C1C=C(NC(=O)CCCCCCCC(NC2C=C(C(=O)C)C=C(C(=O)C)C=2)=O)C=C(C(=O)C)C=1)(=O)C.C(C1C=C(NC(=O)CCCCCCCCC(NC2C=C(C(=O)C)C=C(C(=O)C)C=2)=O)C=C(C(=O)C)C=1)(=O)C.C(C1C=C(NC(=O)CCCCCCCCCCC(NC2C=C(C(=O)C)C=C(C(=O)C)C=2)=O)C=C(C(=O)C)C=1)(=O)C.CC(C1C=CC=C(N)C=1)=O.C(Cl)(=O)CCCC(Cl)=O>>[C:39]([C:37]1[CH:38]=[C:33]([NH:32][C:30](=[O:31])[CH2:29][CH2:28][CH2:27][C:46]([NH:7][C:6]2[CH:5]=[CH:4][CH:10]=[C:9]([C:11](=[O:13])[CH3:12])[CH:8]=2)=[O:48])[CH:34]=[CH:35][CH:36]=1)(=[O:41])[CH3:40]

参加物

11

反応物 10

HCID 74173'-AminoacetophenoneHCID 17887Pentanedioyl dichlorideHCID 463010Cni H1894HCID 15541276HCID 15541276、化合物HCID 15541277HCID 15541277、化合物HCID 15541278HCID 15541278、化合物HCID 15541279HCID 15541279、化合物HCID 15541280HCID 15541280、化合物HCID 15541281N~1~,N~10~-Bis(3,5-diacetylphenyl)decanediamideHCID 15541282HCID 15541282、化合物

生成物 1

HCID 1010291N,N'-bis(3-acetylphenyl)pentanediamide

実験手順

Analogously, the following were prepared from 3,5-diacetylaniline and the corresponding dioyl dichlorides: N,N'-bis(3,5-diacetylphenyl) butanediamide, mp 293-6° C.; N,N'-bis(3,5-diacetylphenyl)hexanediamide, mp 269-70° C.; N,N'-bis(3,5-diacetylphenyl)heptanediamide, mp 200-3° C.; N,N'-bis(3,5-diacetylphenyl)octanediamide, mp 183-4° C.; N,N'-bis(3,5-diacetylphenyl)nonanediamide, mp 179-80° C.; N,N'-bis(3,5-diacetylphenyl)decanediamide, mp 196-9° C.; N,N'-bis(3,5-diacetylphenyl)dodecanediamide, mp 178-9° C.; N,N'-bis(3,5-diacetylphenyl)(isophthalic acid diamide), mp 283-4° C. Also analogously, N,N'-bis(3-acetylphenyl)pentanediamide, mp 174-5° C. was prepared from 3-aminoacetophenone and glutaryl dichloride.

出典と根拠

ORDレコード
ord-a038a1ede9d14bed9a89ded3b152f9a5
出典データセット
uspto-grants-1999_12
特許番号
US06008255

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