Butenylsuccinic acid → n-Butylsuccinic acid

HRID 613966ノート

反応式

HRID 613966 の反応式
[CH:1]([CH:5]([CH2:9][C:10]([OH:12])=[O:11])[C:6]([OH:8])=[O:7])=[CH:2][CH2:3][CH3:4]>CO.[Pt]>[CH2:1]([CH:5]([CH2:9][C:10]([OH:12])=[O:11])[C:6]([OH:8])=[O:7])[CH2:2][CH2:3][CH3:4]

参加物

4

反応物 1

HCID 53797676Butenylsuccinic acid

生成物 1

HCID 3031819n-Butylsuccinic acid

試薬・触媒・溶媒 2

HCID 23939Platinum触媒HCID 887Methanol溶媒

実験手順

40 g. of the butenylsuccinic acid is hydrogenated in methanol over a platinum catalyst to yield n-butylsuccinic acid, m.p. 82°-83° C. Ring closure to n-butyl-succinic anhydride is achieved by mixing it with 100 g. of acetic anhydride and distilling acetic acid as it is formed. The resulting crude product is directly sulfonated by the procedure of 7)b) using corresponding molar amounts of the n-butyl-succinic anhydride and SO3.

出典と根拠

ORDレコード
ord-54dd3fad32cd46f5927e0ce16616efb1
出典データセット
uspto-grants-1979_03
特許番号
US04143020

反応ノート

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