Bis(2-ethylhexyl)amine → 2-chloro-N,N-bis(2-ethylhexyl)-2-phenyl-acetamide

反応式

[CH3:1][CH2:2][CH2:3][CH2:4][CH:5]([CH2:8][NH:9][CH2:10][CH:11]([CH2:14][CH2:15][CH2:16][CH3:17])[CH2:12][CH3:13])[CH2:6][CH3:7].[Cl:18][CH:19]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)[C:20](Cl)=[O:21]>>[Cl:18][CH:19]([C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)[C:20]([N:9]([CH2:8][CH:5]([CH2:6][CH3:7])[CH2:4][CH2:3][CH2:2][CH3:1])[CH2:10][CH:11]([CH2:12][CH3:13])[CH2:14][CH2:15][CH2:16][CH3:17])=[O:21]

参加物

反応物 2

HCID 7791Bis(2-ethylhexyl)amine

HCID 102902Chloro(phenyl)acetyl chloride

生成物 1

HCID 1180595492-chloro-N,N-bis(2-ethylhexyl)-2-phenyl-acetamide収率 96%

実験手順

Step A is conducted starting from 2,2′-diethylhexylamine and α-chlorophenylacetyl chloride and leads to 2-chloro-N,N-bis(2-ethylhexyl)-2-phenyl-acetamide (Yield: 96%) for which the characterisations by 1H and 13C NMR are given below:

出典と根拠

ORDレコード: ord-0e9e4199149b43188a2b7b866cc8e30c
出典データセット: uspto-grants-2016_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US09441285B2

反応ノート

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