Water → 1-Acetamido-2-amino-4-benzylthiobenzene
反応式
[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][C:6]=1[N+:19]([O-])=O)(=[O:3])[CH3:2].O>[Fe].CO>[C:1]([NH:4][C:5]1[CH:10]=[CH:9][C:8]([S:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[CH:7][C:6]=1[NH2:19])(=[O:3])[CH3:2]参加物
5
実験手順
2.4 G. of 1-acetamido-2-nitro-4-benzylthiobenzene is treated with 2.4 g. iron powder and 1.2 g. ferrous sulfate in a mixture of 60 ml. water and 240 ml. methanol, at reflux for 4 hours. The mixture is then filtered, the filtrate concentrated and the residue recrystallized from benzene. Pure 1-acetamido-2-amino-4-benzylthiobenzene is obtained.
後処理
- filtrationThe mixture is then filtered
- concentrationthe filtrate concentrated
- customthe residue recrystallized from benzene
出典と根拠
- ORDレコード
- ord-1b56a93dea7345e5adf1da1fd8c48dbc
- 出典データセット
- uspto-grants-1978_02
- 特許番号
- US04072696
反応ノート
読み込み中…