Methanol → HCID 21328029、化合物

HRID 616118ノート

反応式

HRID 616118 の反応式
[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([CH2:10][CH:11]=[CH2:12])=[O:9])=[CH:4][C:3]=1[N+:13]([O-])=O.CO>[Fe].O>[NH2:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([CH2:10][CH:11]=[CH2:12])=[O:9])=[CH:4][C:3]=1[NH2:13]

参加物

5

反応物 2

HCID 887MethanolHCID 203710631-Amino-2-nitro-4-(prop-2-en-1-ylsulfinyl)-benzene

生成物 1

HCID 21328029HCID 21328029、化合物

試薬・触媒・溶媒 2

HCID 23925Iron触媒HCID 962Water溶媒

実験手順

2 G. of 1-amino-2-nitro-4-(prop-2-en-1-ylsulfinyl)-benzene is treated for four hours in a refluxing mixture of 160 ml. methanol and 40 ml. water with 4 g. iron powder (added in two portions) and 1 g. ferrous sulfate. The mixture is filtered, and the filtrate concentrated. The residue is dissolved in chloroform and washed with water, then the solvent evaporated affording 1,2-diamino-4-(prop-2-en-1-ylsulfinyl)benzene.

後処理

  1. filtrationThe mixture is filtered
  2. concentrationthe filtrate concentrated
  3. dissolutionThe residue is dissolved in chloroform
  4. washwashed with water
  5. customthe solvent evaporated

出典と根拠

ORDレコード
ord-ffb8c09957a94dbe9f30de9dbad06fb3
出典データセット
uspto-grants-1978_02
特許番号
US04072696

反応ノート

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