化工社化工社 化学情報印刷レポート · 研究参考用
Methyl heptanoate → 5-Hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl heptanoate | HCID 7826 | — |
| 反応物 | 1-Hexanethiol | HCID 8106 | — |
| 反応物 | Potassium tert-butoxide | HCID 23665647 | — |
| 生成物 | 5-Hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester | HCID 54239364 | 61.3% |
反応手順
In accordance with the process of Example 17, potassium t-butoxide, (336 mg; 3 m mol), n-hexyl mercaptan (354 mg; 3 m mol) and 2-oxo-bicyclo 3.1.0!hexane-1-carboxylic acid methyl ester (463 mg; 3 m mol) were used to obtain 500 mg of 5-hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04073799 |
| 出典データセット | uspto-grants-1978_02 |
| ORD ID | ord-6813b7b5544b483e9e3dd6ffc96b5d32 |
| 出典メモ | uspto-grants-1978_02 |