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HRID616297

反应详情

EQUATION

反应方程式

HRID 616297 的结构方程式

REACTANTS

反应物

3
结构：CCCCCCC(=O)OC
HCID7826

Methyl heptanoate

C8H16O2

结构：CCCCCCS
HCID8106

1-Hexanethiol

C6H14S

结构：CC(C)(C)[O-].[K+]
HCID23665647

2-Methyl-2-propanol, potassium salt

C4H9KO

PRODUCTS

生成物

1
结构：CCCCCCSCC1CCC(=O)C1C(=O)OC
HCID54239364

Methyl 2-[(hexylsulfanyl)methyl]-5-oxocyclopentane-1-carboxylate

C14H24O3S

收率 61.3%

PROCEDURE

实验过程

In accordance with the process of Example 17, potassium t-butoxide, (336 mg; 3 m mol), n-hexyl mercaptan (354 mg; 3 m mol) and 2-oxo-bicyclo 3.1.0!hexane-1-carboxylic acid methyl ester (463 mg; 3 m mol) were used to obtain 500 mg of 5-hexylthiomethyl-2-oxo-cyclopentanecarboxylic acid methyl ester.