tert-Butyl hydroperoxide → HCID 20367911、化合物

HRID 616579ノート

反応式

HRID 616579 の反応式
[C:1]([N:5]=[N:6][C:7](Cl)([CH2:9][C:10]([CH3:13])([CH3:12])[CH3:11])[CH3:8])([CH3:4])([CH3:3])[CH3:2].[C:15]([O:19][OH:20])([CH3:18])([CH3:17])[CH3:16].[OH-].[Na+]>CO>[C:1]([N:5]=[N:6][C:7]([O:20][O:19][C:15]([CH3:18])([CH3:17])[CH3:16])([CH2:9][C:10]([CH3:13])([CH3:12])[CH3:11])[CH3:8])([CH3:4])([CH3:3])[CH3:2]

参加物

5

反応物 3

HCID 6410tert-Butyl hydroperoxideHCID 14798Sodium HydroxideHCID 23344794(E)-1-tert-Butyl-2-(2-chloro-4,4-dimethylpentan-2-yl)diazene

生成物 1

HCID 20367911HCID 20367911、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

The 2-t-butylazo-2-(t-butylperoxy)-4,4-dimethylpentane was prepared in 78% crude yield from 3.36 grams (.02moles) of 2-t-butylazo-2-chloro-4,4-dimethylpentane, 2.77 grams (.0277 moles) of 90% t-butyl hydroperoxide and 2.0 grams (.025 moles) of 50% NaOH in 20 ml. of methanol. The procedure was the same as that described in Example X.

出典と根拠

ORDレコード
ord-b5ec473fe6b54fbab4f1327eeba147c5
出典データセット
uspto-grants-1978_02
特許番号
US04075199

反応ノート

読み込み中…