Tetrahydrofuran → HCID 13755456、化合物

HRID 620769ノート

反応式

HRID 620769 の反応式
[O:1]=[C:2]([NH:23][C:24]1[CH:32]=[CH:31][CH:30]=[CH:29][C:25]=1[C:26]([OH:28])=[O:27])[C:3](=[CH:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1)[C:4]([NH:6][C:7]1[CH:15]=[CH:14][CH:13]=[CH:12][C:8]=1[C:9]([OH:11])=[O:10])=[O:5].C1COCC1.C(=O)([O-])[O-].[Ca+2:42]>O>[Ca+2:42].[O:5]=[C:4]([NH:6][C:7]1[CH:15]=[CH:14][CH:13]=[CH:12][C:8]=1[C:9]([O-:11])=[O:10])[C:3](=[CH:16][C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1)[C:2]([NH:23][C:24]1[CH:32]=[CH:31][CH:30]=[CH:29][C:25]=1[C:26]([O-:28])=[O:27])=[O:1]

参加物

5

反応物 3

HCID 8028TetrahydrofuranHCID 10112Calcium CarbonateHCID 3062455Benzoic acid, 2,2'-((1,3-dioxo-2-(phenylmethylene)-1,3-propanediyl)diimino)bis-

生成物 1

HCID 13755456HCID 13755456、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The Compound 11 (430 mg 1 mmol) was treated with THF (20 ml) and water (10 ml), and further with calcium carbonate (100 mg, 1 mmol), and the mixture was stirred at room temperature for 24 hours. The reaction mixture was filtered by suction, and the solvent was removed from the filtrate. The residue was washed with acetone to give the desired calcium salt in pale yellow solid (420 mg, yield, 89.6%). m.p., 300° C. or higher.

後処理

  1. filtrationThe reaction mixture was filtered by suction
  2. customthe solvent was removed from the filtrate
  3. washThe residue was washed with acetone

出典と根拠

ORDレコード
ord-ff8fa29cb6bb4a02a895080fe530ac29
出典データセット
uspto-grants-1989_04
特許番号
US04822791

反応ノート

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