Tetrabutylammonium Fluoride → HCID 85561342、化合物
反応式
[F:1]C(F)(F)C([O-])=O.[CH3:8][O:9][C:10]1[CH:15]=[CH:14][C:13]([I+:16][C:17]2[CH:22]=[CH:21][C:20]([O:23][CH3:24])=[CH:19][CH:18]=2)=[CH:12][CH:11]=1.CCCC[N+](CCCC)(CCCC)CCCC.[F-]>O1CCCC1>[F-:1].[CH3:24][O:23][C:20]1[CH:19]=[CH:18][C:17]([I+:16][C:13]2[CH:14]=[CH:15][C:10]([O:9][CH3:8])=[CH:11][CH:12]=2)=[CH:22][CH:21]=1参加物
4
実験手順
To a mixture of 454 mg (1 mmol) Bis(p-methoxyphenyl)iodonium trifluoroacetate and 262 mg (1 mmol) anhydrous TBAF was added 1 mL of dry tetrahydrofuran (THF). The solution was allowed to stand for 1 hour, the white precipitate was collected and washed with 3×0.5 mL THF. Calculated yield: 288.7 mg (802%)
後処理
- customthe white precipitate was collected
- washwashed with 3×0.5 mL THF
出典と根拠
- ORDレコード
- ord-f479d45903174df285e0d47d03d5727f
- 出典データセット
- uspto-grants-2016_04
- 特許番号
- US09302990B2
反応ノート
読み込み中…