N'-(propan-2-ylidene)(tert-butoxy)carbohydrazide → N'-(propan-2-yl)(tert-butoxy)carbohydrazide

HRID 624626ノート

反応式

HRID 624626 の反応式
[CH3:1][C:2](=[N:4][NH:5][C:6]([O:8][C:9]([CH3:12])([CH3:11])[CH3:10])=[O:7])[CH3:3].[H][H]>[Pd].C(O)(=O)C.CO>[CH:2]([NH:4][NH:5][C:6]([O:8][C:9]([CH3:11])([CH3:10])[CH3:12])=[O:7])([CH3:3])[CH3:1]

参加物

6

反応物 2

HCID 11435207N'-(propan-2-ylidene)(tert-butoxy)carbohydrazideHCID 178418361HCID 178418361、化合物

生成物 1

HCID 11217534N'-(propan-2-yl)(tert-butoxy)carbohydrazide

試薬・触媒・溶媒 3

HCID 23938Palladium触媒HCID 176Acetic Acid溶媒HCID 887Methanol溶媒

実験手順

tert-Butyl 2-(propan-2-ylidene)hydrazinecarboxylate 2 was reduced with palladium catalyst on carbon with hydrogen gas in acetic acid and methanol to give tert-butyl 2-isopropylhydrazinecarboxylate 3 (CAS Reg. No. 16689-35-3).

出典と根拠

ORDレコード
ord-bde8e15a9ed14be587b08c5b6b393b39
出典データセット
uspto-grants-2016_04
特許番号
US09303043B2

反応ノート

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