Glucaric Acid → Adipic Acid
反応式
[O:1]=[C:2]([OH:14])[C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([C:11]([OH:13])=[O:12])O)O)O)O.O=C(O)[C@@H]([C@H]([C@H]([C@@H](C(O)=O)O)O)O)O>[Re]>[C:11]([OH:13])(=[O:12])[CH2:9][CH2:7][CH2:5][CH2:3][C:2]([OH:14])=[O:1]参加物
4
実験手順
Further, as described above, the starting material (glucaric acid or galactaric acid), rhenium catalyst, and acid catalyst are added to the reaction solvent, and reacted together at a proper temperature for a proper reaction time, then separated and purified with a conventional method (e.g., purification with silica column) to obtain glucaric acid ester or galactaric acid ester as an intermediate of adipic acid. In one embodiment, the reaction temperature ranges from 100 to 200° C., and the reaction time is 12 to 24 hours.
後処理
- additionare added to the reaction solvent
- customreacted together at a proper temperature for a proper reaction time
- customseparated
- custompurified with a conventional method (e.g., purification with silica column)
出典と根拠
- ORDレコード
- ord-e4d92eb81e1047428d952ffc9a9ab295
- 出典データセット
- uspto-grants-2016_09
- 特許番号
- US09447012B2
反応ノート
読み込み中…