Triphenylphosphine → (2S,5R)-tert-butyl 5-(N-(allyloxy)-2-nitrophenylsulfonamido)-3-(2-((tert-butyldimethylsilyl)oxy)ethyl)-2-(((tert-butyldimethylsilyl)oxy)methyl)-5,6-dihydropyridine-1(2H)-carboxylate

反応式

OC1CN(C([O-])=O)CC=C1.[Si:11]([O:18][CH2:19][CH2:20][C:21]1[C@@H:22]([CH2:35][O:36][Si:37]([C:40]([CH3:43])([CH3:42])[CH3:41])([CH3:39])[CH3:38])[N:23]([C:28]([O:30][C:31]([CH3:34])([CH3:33])[CH3:32])=[O:29])[CH2:24][C@@H:25](O)[CH:26]=1)([C:14]([CH3:17])([CH3:16])[CH3:15])([CH3:13])[CH3:12].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[CH2:63]([O:66][NH:67][S:68]([C:71]1[CH:76]=[CH:75][CH:74]=[CH:73][C:72]=1[N+:77]([O-:79])=[O:78])(=[O:70])=[O:69])[CH:64]=[CH2:65].N(C(OC(C)C)=O)=NC(OC(C)C)=O>C1(C)C=CC=CC=1>[CH2:63]([O:66][N:67]([C@H:25]1[CH2:24][N:23]([C:28]([O:30][C:31]([CH3:33])([CH3:32])[CH3:34])=[O:29])[C@H:22]([CH2:35][O:36][Si:37]([C:40]([CH3:41])([CH3:43])[CH3:42])([CH3:39])[CH3:38])[C:21]([CH2:20][CH2:19][O:18][Si:11]([C:14]([CH3:15])([CH3:16])[CH3:17])([CH3:12])[CH3:13])=[CH:26]1)[S:68]([C:71]1[CH:76]=[CH:75][CH:74]=[CH:73][C:72]=1[N+:77]([O-:79])=[O:78])(=[O:70])=[O:69])[CH:64]=[CH2:65]