2-Cyclohexylhepta-1,6-dien-3-ol → 2-Cyclohexyl-1,6-heptadien-3-one
反応式
[CH:1]1([C:7]([CH:9]([OH:14])[CH2:10][CH2:11][CH:12]=[CH2:13])=[CH2:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1>CCCCCC.O=[Mn]=O>[CH:1]1([C:7]([C:9](=[O:14])[CH2:10][CH2:11][CH:12]=[CH2:13])=[CH2:8])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1参加物
4
実験手順
2-Cyclohexyl-hepta-1,6-dien-3-ol (85 g, 0.44 mol) were oxidized with MnO2 (804 g, 9.2 mol) in 2 l of hexane at RT. After stirring for 96 hours, the reaction mixture was filtered over Celite and concentrated in vacuo yielding 71 g of a yellow oil. Distillation (0.04 Torr/70° C.) yielded 43.5 g (51%) of pure product.
後処理
- filtrationthe reaction mixture was filtered over Celite
- concentrationconcentrated in vacuo
出典と根拠
- ORDレコード
- ord-cd81a043ff584f3aa1dd652baf5b7a38
- 出典データセット
- uspto-grants-2001_02
- 特許番号
- US06184419B2
反応ノート
読み込み中…