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Methyl propiolate → HCID 178515908、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl propiolate | HCID 13536 | — |
| 反応物 | 3-Aminocyclohex-2-en-1-one | HCID 78892 | — |
| 生成物 | HCID 178515908 | HCID 178515908 | 21.3% |
反応手順
A mixture of 3-amino-2-cyclohexen-1-one (25.0 g, 224.9 mmol) and methyl propiolate (23.6 g, 281 mmol) was heated to reflux for 1 h. The mixture was cooled and the solid was collected by filtration, washing with THF, to give 7.8 g (21%) of the title compound as a yellow solid. [M+H] calc'd for C9H9NO2, 164. found 164.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US09447046B2 |
| 出典データセット | uspto-grants-2016_09 |
| ORD ID | ord-3f3767687e84472091071ae2d9152061 |
| 出典メモ | uspto-grants-2016_09 |