関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1-Chloro-4-nitrobenzene | HCID 7474 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | Potassium Acetate | HCID 517044 | — |
| 溶媒 | 1-Butanol | HCID 263 | — |
| 生成物 | 1,1'-Oxybis(4-nitrobenzene) | HCID 7568 | — |
反応手順
A 250 ml shaker bomb is charged with 79 g (0.50 mole) p-nitrochlorobenzene, 43 g n-butanol, 3 g (0.03 mole) potassium acetate, and 30 g (0.28 mole) sodium carbonate. The reactor is purged with nitrogen and heated to and maintained at 200° C. under autogenous pressure for 9 hours. No increase in pressure is observed and no 4,4'-dinitrodiphenyl ether is formed. This example illustrates that the reaction will not proceed using a protic solvent.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04558164 |
|---|
| 出典データセット | uspto-grants-1985_12 |
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| ORD ID | ord-75fdddeaadc445858041a462c4163a6b |
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| 出典メモ | uspto-grants-1985_12 |
|---|
