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HRID637820

反应详情

EQUATION

反应方程式

HRID 637820 的结构方程式

REACTANTS

反应物

3
结构：O=[N+]([O-])c1ccc(Cl)cc1
HCID7474

1-Chloro-4-nitrobenzene

C6H4ClNO2

结构：O=C([O-])[O-].[Na+].[Na+]
HCID10340

Carbonic acid sodium salt (1:2)

CNa2O3

结构：CC(=O)[O-].[K+]
HCID517044

Potassium acetate

C2H3KO2

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1ccc(Oc2ccc([N+](=O)[O-])cc2)cc1
HCID7568

1,1'-Oxybis(4-nitrobenzene)

C12H8N2O5

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCCCO
溶剂HCID263

1-Butanol

C4H10O

CONDITIONS

反应条件

温度
200 °C

PROCEDURE

实验过程

A 250 ml shaker bomb is charged with 79 g (0.50 mole) p-nitrochlorobenzene, 43 g n-butanol, 3 g (0.03 mole) potassium acetate, and 30 g (0.28 mole) sodium carbonate. The reactor is purged with nitrogen and heated to and maintained at 200° C. under autogenous pressure for 9 hours. No increase in pressure is observed and no 4,4'-dinitrodiphenyl ether is formed. This example illustrates that the reaction will not proceed using a protic solvent.

WORKUP

后处理

  1. customThe reactor is purged with nitrogen
  2. temperatureheated to and
  3. temperatureNo increase in pressure