Hydrogen Peroxide → HCID 20482309、化合物

HRID 648178ノート

反応式

HRID 648178 の反応式
[CH2:1]([N:4]([CH2:12][CH2:13][CH3:14])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][OH:11])[CH2:2][CH3:3].[OH:15]O>[Pt]>[CH2:12]([N+:4]([O-:15])([CH2:1][CH2:2][CH3:3])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][OH:11])[CH2:13][CH3:14]

参加物

4

反応物 2

HCID 784Hydrogen PeroxideHCID 1426456-Dipropylamino-1-hexanol

生成物 1

HCID 20482309HCID 20482309、化合物収率 4.2%

試薬・触媒・溶媒 1

HCID 23939Platinum触媒

実験手順

To 44 g of dipropyl-6-hydroxyhexyl amine was added slowly 11.0 g of 30% hydrogen peroxide. After stirring overnight at room temperature, the reaction mixture was stirred with 0.2 platinum black for several hours followed by filtration through Hyflo® filter-aid. After extraction with 50 ml ether, the aqueous phase was evaporated in vacuo to remove most of the water, leaving 2.0 g of dipropyl-6-hydroxyhexyl amine oxide. NMR analysis showed that there was 30% water present.

後処理

  1. filtrationfollowed by filtration through Hyflo®
  2. filtrationfilter-aid
  3. extractionAfter extraction with 50 ml ether
  4. customthe aqueous phase was evaporated in vacuo
  5. customto remove most of the water

出典と根拠

ORDレコード
ord-b8a132a3c865428998993a1778251078
出典データセット
uspto-grants-1983_10
特許番号
US04411893

反応ノート

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