3-Chloroaniline → N-(3-chlorophenyl)valine

反応式

Br[CH:2]([CH:20]([CH3:22])[CH3:21])[C:3]([O:5]CC1C=CC=C(OC2C=CC=CC=2)C=1)=[O:4].[Cl:23][C:24]1[CH:25]=[C:26]([CH:28]=[CH:29][CH:30]=1)[NH2:27]>>[Cl:23][C:24]1[CH:25]=[C:26]([NH:27][C@H:2]([C:3]([OH:5])=[O:4])[CH:20]([CH3:22])[CH3:21])[CH:28]=[CH:29][CH:30]=1

参加物

反応物 2

HCID 79323-Chloroaniline

HCID 13229492m-Phenoxybenzyl alpha-bromoisovalerate

生成物 1

HCID 54529580N-(3-chlorophenyl)valine

実験手順

Following the procedure of Example 1, m-phenoxybenzyl α-bromoisovalerate is reacted with 3-chloroaniline to yield the m-phenoxybenzyl ester of N-(3-chlorophenyl)valine, MS m/e 409.2 (M+).

出典と根拠

ORDレコード: ord-eedc43d01f1a4adcaeee1f04df54832b
出典データセット: uspto-grants-1983_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04411912

反応ノート

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