Dimethyloctylamine → HCID 178419187、化合物

HRID 649502

反応式

HRID 649502 の反応式
[CH2:1]([N:9]([CH3:11])[CH3:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[BH3:12].C(N(CC)CC)C>C(N(CC)CC)C>[BH3:12].[CH2:1]([N:9]([CH3:11])[CH3:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

4

反応物 2

HCID 16224DimethyloctylamineHCID 264094borane;N,N-diethylethanamine

生成物 1

HCID 178419187HCID 178419187、化合物収率 89%

試薬・触媒・溶媒 1

HCID 8471Triethylamine溶媒

実験手順

Octyldimethylamine (20.4 grams; 0.130 mole) was heated with triethylamine borane (1.9 grams; 0.130 mole) at reflux temperature until 12.8 grams (98%) of triethylamine had been collected in a cold trap. The reaction residue was distilled at reduced pressure to give N-octyl-N,N-dimethylamine borane boiling at 98°-100° C./0.9 mm. Hg. (19.6 grams; 89% yield).

後処理

  1. customhad been collected in a cold trap
  2. distillationThe reaction residue was distilled at reduced pressure

出典と根拠

ORDレコード
ord-d602c547b2d447c5a70a59f83b9251c5
出典データセット
uspto-grants-1988_04
特許番号
US04740504

関連ノート

読み込み中…