Ethanolamine → HCID 650462、化合物

反応式

Cl[C:2]1[C:3](=[O:20])[NH:4][C:5]2[CH:19]=[CH:18][CH:17]=[C:7]3[C:8](=[O:16])[C:9]4[CH:15]=[CH:14][CH:13]=[CH:12][C:10]=4[C:11]=1[C:6]=23.[CH2:21]([CH2:23][NH2:24])[OH:22].[C:25]([O-])(=O)C.[Na+]>CO>[OH:22][CH2:21][CH2:23][NH:24][C:2]1[C:3](=[O:20])[N:4]([CH3:25])[C:5]2[CH:19]=[CH:18][CH:17]=[C:7]3[C:8](=[O:16])[C:9]4[CH:15]=[CH:14][CH:13]=[CH:12][C:10]=4[C:11]=1[C:6]=23

参加物

実験手順

A mixture of 1-chloro-3H-dibenz[f,ij]isoquinoline-2,7-dione (1.8 g), ethanolamine (14 ml), sodium acetate (1 g), and a trace of cupric acetate was heated at 100°-110° C. until reaction appeared to be complete (~1 hr). After cooling, methanol (10 ml) was added to the reaction mixture at about 80° C. Upon further cooling the product crystallized in the form of yellow solid. After being isolated by filtration and recrystallized from methyl Cellosolve, the product melted at 203°-206° C. and had an absorption maxium at 441 nm in the visible spectrum in acetone solution, thus imparting a greenish-yellow color thereto. The structure is as follows: ##STR5##