Benzoyl chloride → Allyl benzoate
反応式
C(Cl)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10](=[O:19])([O:15][CH2:16][CH:17]=[CH2:18])OCC=C>[Cl-].[Zn+2].[Cl-]>[C:10]([O:15][CH2:16][CH:17]=[CH2:18])(=[O:19])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1参加物
4
反応条件
- 温度
- 60 °C
実験手順
In a glass reactor benzoyl chloride (7.03 g, 0.05 mole), diallyl carbonate (7.1 g, 0.05 mole) and zinc chloride (0.136 g, 0.001 mole) were combined. The reacinitiated at room temperature. After heating at 60° C. for 3 hours and heating at 80° C. for an additional 3 hours, the reaction was discontinued. Distillation gave 6.65 g (78 percent yield) of allyl benzoate which was identified by nuclear magnetic resonance spectroscopy.
後処理
- customreacinitiated at room temperature
- temperatureheating at 80° C. for an additional 3 hours
- distillationDistillation
出典と根拠
- ORDレコード
- ord-39ac0fe3490b4b4ca1802b534a76f6ac
- 出典データセット
- uspto-grants-1986_09
- 特許番号
- US04612386
反応ノート
読み込み中…