Benzoyl chloride → Allyl benzoate

HRID 65133

反応式

HRID 65133 の反応式
C(Cl)(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10](=[O:19])([O:15][CH2:16][CH:17]=[CH2:18])OCC=C>[Cl-].[Zn+2].[Cl-]>[C:10]([O:15][CH2:16][CH:17]=[CH2:18])(=[O:19])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

4

反応物 2

HCID 7412Benzoyl chlorideHCID 84764Carbonic acid, di-2-propen-1-yl ester

生成物 1

HCID 11406Allyl benzoate収率 82%

試薬・触媒・溶媒 1

HCID 3007855Zincchloride触媒

反応条件

温度
60 °C

実験手順

In a glass reactor benzoyl chloride (7.03 g, 0.05 mole), diallyl carbonate (7.1 g, 0.05 mole) and zinc chloride (0.136 g, 0.001 mole) were combined. The reacinitiated at room temperature. After heating at 60° C. for 3 hours and heating at 80° C. for an additional 3 hours, the reaction was discontinued. Distillation gave 6.65 g (78 percent yield) of allyl benzoate which was identified by nuclear magnetic resonance spectroscopy.

後処理

  1. customreacinitiated at room temperature
  2. temperatureheating at 80° C. for an additional 3 hours
  3. distillationDistillation

出典と根拠

ORDレコード
ord-39ac0fe3490b4b4ca1802b534a76f6ac
出典データセット
uspto-grants-1986_09
特許番号
US04612386

関連ノート

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