Tetrahydrofuran → (Buta-1,3-dien-2-yl)(trimethoxy)silane
反応式
[CH3:1][O:2][Si:3](OC)([O:6][CH3:7])[O:4][CH3:5].O1[CH2:14][CH2:13][CH2:12][CH2:11]1>>[CH3:1][O:2][Si:3]([O:6][CH3:7])([O:4][CH3:5])[C:12]([CH:13]=[CH2:14])=[CH2:11]参加物
3
反応条件
- 温度
- 0 °C
実験手順
4.1 ml of the tetrahydrofuran solution of magnesium 2-(1,3-butadienyl)chloride and 6 ml of dried tetrahydrofuran were charged into a reactor in the stream of argon. Subsequently, the reactor was cooled down to 0° C., followed by gentle dropping of 1.2 ml (8 mmols) of tetramethoxysilane. While the reaction temperature was kept at 0° C., the reaction was continued for 30 minutes. After completion of the reaction, the solvent was distilled off to obtain 2-(trimethoxy)silyl-1,3-butadiene (yield: 65%).
後処理
- customwas kept at 0° C.
- customAfter completion of the reaction
- distillationthe solvent was distilled off
出典と根拠
- ORDレコード
- ord-54c116a5d9f84f239e2d9901dced3329
- 出典データセット
- uspto-grants-1987_06
- 特許番号
- US04677216
反応ノート
読み込み中…