Methyl iodide → HCID 271998、化合物
反応式
CS[CH2:3][C:4]1[O:5][C:6]2[C:11]([C:12](=[O:14])[CH:13]=1)=[CH:10][CH:9]=[CH:8][CH:7]=2.C[I:16]>ClCCl>[I:16][CH2:3][C:4]1[O:5][C:6]2[C:11]([C:12](=[O:14])[CH:13]=1)=[CH:10][CH:9]=[CH:8][CH:7]=2参加物
4
実験手順
8 g of 2-methylthiomethyl-4-oxo-4H-chromene, 200 ml of methyl iodide and 26 ml of dichloromethane are brought to reflux with stirring for 4 days. The precipitate is filtered off, the excess solvents and reagents are evaporated off, the residue is taken up with ethyl ether and the organic phase is washed with sodium thiosulfate solution, dried and evaporated.
後処理
- temperatureto reflux
- filtrationThe precipitate is filtered off
- customthe excess solvents and reagents are evaporated off
- washthe organic phase is washed with sodium thiosulfate solution
- customdried
- customevaporated
出典と根拠
- ORDレコード
- ord-c1e1cedb3d38419a9113e8e0273f4061
- 出典データセット
- uspto-grants-1992_07
- 特許番号
- US05134147
反応ノート
読み込み中…