Sodium Hypochlorite → Sodium 3,3-dimethyl-2-oxobutyrate

HRID 65490

反応式

HRID 65490 の反応式
[CH3:1][C:2]([CH3:9])([CH3:8])[CH:3]([OH:7])[C:4]([O-:6])=[O:5].[Na+:10].Cl[O-].[Na+]>O.[Ru](=O)=O.O>[CH3:1][C:2]([CH3:9])([CH3:8])[C:3](=[O:7])[C:4]([O-:6])=[O:5].[Na+:10]

参加物

5

反応物 2

HCID 23665760Sodium HypochloriteHCID 23694960Sodium 3,3-dimethyl-2-hydroxybutyrate

生成物 1

HCID 23674764Sodium 3,3-dimethyl-2-oxobutyrate

試薬・触媒・溶媒 2

HCID 16211523Ruthenium dioxide hydrate触媒HCID 962Water溶媒

実験手順

Sodium 3,3-dimethyl-2-hydroxybutyrate and ruthenium dioxide hydrate are added to water, the pH rendered alkaline, and sodium hypochlorite is slowly added to produce sodium 3,3-dimethyl-2-oxobutyrate in high yield and purity. The solid catalyst is filtered off and may be re-used while the filtrate can be directly used in further synthesis.

後処理

  1. additionis slowly added

出典と根拠

ORDレコード
ord-0abcb0c150bc4175a08041240e6ed897
出典データセット
uspto-grants-1986_09
特許番号
US04614822

関連ノート

読み込み中…