Benzyl Alcohol → 4-(Benzylthio)phenol
反応式
[SH:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.[CH2:9](O)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1>C1(C)C(S(O)(=O)=O)=CC=CC=1.C1C=CC=CC=1>[CH2:9]([S:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1)[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1参加物
5
実験手順
4-(Benzylthio)phenol was prepared as follows. Seventy grams of 4-mercaptophenol, 30 drops of toluene sulfonic acid and 100 milliliters of benzene were placed in a flask. Eighty-three grams of benzyl alcohol were added and the flask contents stirred at reflux for five hours to collect the water formed. A white substance precipitated from solution and was filtered. It was washed with hexane. The substance had a melting point of 96° C. to 98° C., a percent sulfur of 14.4 and a hydroxyl number of 259.
後処理
- temperatureat reflux for five hours
- customto collect the water
- customformed
- customA white substance precipitated from solution
- filtrationwas filtered
- washIt was washed with hexane
出典と根拠
- ORDレコード
- ord-b73cc56b7eb04dffbafb646185db42db
- 出典データセット
- uspto-grants-1978_12
- 特許番号
- US04128530
反応ノート
読み込み中…