Benzamide, 3-nitro-N-(3-nitrophenyl)- → Benzamide, 3-amino-N-(3-aminophenyl)-

HRID 65610ノート

反応式

HRID 65610 の反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:19]=[CH:20][CH:21]=1)[C:7]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([N+:16]([O-])=O)[CH:11]=1)=[O:8])([O-])=O.[H][H]>[Pd].O1CCOCC1>[NH2:1][C:4]1[CH:5]=[C:6]([CH:19]=[CH:20][CH:21]=1)[C:7]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([NH2:16])[CH:11]=1)=[O:8]

参加物

5

反応物 2

HCID 66861Benzamide, 3-nitro-N-(3-nitrophenyl)-HCID 178418361HCID 178418361、化合物

生成物 1

HCID 66859Benzamide, 3-amino-N-(3-aminophenyl)-

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 312751,4-Dioxane溶媒

実験手順

A solution of 14.3 g of 3,3'-dinitrobenzanilide in 150 ml. of dioxane is hydrogenated at three atmospheres of hydrogen using 1 g. of 10% palladium-on-charcoal catalyst. The catalyst is removed by filtration and the filtrate evaporated to dryness. The residue is recrystallized from ethanol. There is obtained 8.72 g. of material melting at 123°-4°.

後処理

  1. customThe catalyst is removed by filtration
  2. customthe filtrate evaporated to dryness
  3. customThe residue is recrystallized from ethanol
  4. customThere is obtained 8.72 g

出典と根拠

ORDレコード
ord-4e2946f77f2c40ab8b38465e36dfb128
出典データセット
uspto-grants-1978_12
特許番号
US04128570

反応ノート

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