3,5-dinitro-N-(3-nitrophenyl)benzamide → 3,3',5-Triaminobenzanilide
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:19]=[C:20]([N+:22]([O-])=O)[CH:21]=1)[C:7]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([N+:16]([O-])=O)[CH:11]=1)=[O:8])([O-])=O.[H][H]>[Pd].O1CCOCC1>[NH2:22][C:20]1[CH:19]=[C:6]([CH:5]=[C:4]([NH2:1])[CH:21]=1)[C:7]([NH:9][C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([NH2:16])[CH:11]=1)=[O:8]参加物
5
実験手順
A solution of 13.29 gm. (0.04 mole) of 3,3',5-trinitrobenzanilide in 150 ml. of dioxane is hydrogenated at three atmospheres of hydrogen using 1 gm. of 10% palladium-on-charcoal catalyst. The catalyst is removed by filtration, the filtrate evaporated to dryness under reduced pressure, and the residue dried by distilling 200 ml. of benzene from the reaction mixture.
後処理
- customThe catalyst is removed by filtration
- customthe filtrate evaporated to dryness under reduced pressure
- customthe residue dried
- distillationby distilling 200 ml
出典と根拠
- ORDレコード
- ord-14dbbd04960841d7b3e26d55be517ba3
- 出典データセット
- uspto-grants-1978_12
- 特許番号
- US04128570
反応ノート
読み込み中…