Diethyl N,N'-(oxydi-p-phenylene)dioxamate → HCID 21315031、化合物
反応式
[O:1]([C:16]1[CH:21]=[CH:20][C:19]([NH:22][C:23](=[O:29])[C:24]([O:26]CC)=[O:25])=[CH:18][CH:17]=1)[C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9](=[O:15])[C:10]([O:12]CC)=[O:11])=[CH:4][CH:3]=1>[OH-].[Na+]>[O:1]([C:16]1[CH:21]=[CH:20][C:19]([NH:22][C:23](=[O:29])[C:24]([OH:26])=[O:25])=[CH:18][CH:17]=1)[C:2]1[CH:3]=[CH:4][C:5]([NH:8][C:9](=[O:15])[C:10]([OH:12])=[O:11])=[CH:6][CH:7]=1参加物
3
実験手順
Diethyl N,N'-(oxydi-p-phenylene)dioxamate (2.0 gm.) is stirred at room temperature for 3 hours in 1.0 N sodium hydroxide (50 ml.). The solid is collected by filtration and dissolved in water. The pH is adjusted to pH=3 with concentrated hydrochloric acid and the desired product collected by filtration (1.6 gm., mp >320°). The ir spectrum is consistent with the assigned structure.
後処理
- filtrationThe solid is collected by filtration
- dissolutiondissolved in water
- filtrationthe desired product collected by filtration (1.6 gm., mp >320°)