38263-46-6 → HCID 55300761、化合物

HRID 656253ノート

反応式

HRID 656253 の反応式
[C@H:1]12[O:7][C@H:4]([CH:5]=[CH:6]1)[CH2:3][C@H:2]2[C:8]([OH:10])=[O:9]>C(O)C.[Pd]>[C@H:1]12[O:7][C@@H:4]([CH2:5][CH2:6]1)[CH2:3][C@H:2]2[C:8]([OH:10])=[O:9]

参加物

4

反応物 1

HCID 983398038263-46-6

生成物 1

HCID 55300761HCID 55300761、化合物

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

A solution of 1 mmol of (1S,2R,4S)-7-oxabicyclo[2.2.1]-hept-5-ene-2-carboxylic acid [185840-15-7] in 30 ml of ethanol is hydrogenated in the presence of 0.150 g of Pd/C 10% at room temperature until conversion is complete. The reaction mixture is clarified by filtration, and the filtrate is evaporated. The title compound is obtained from the residue by flash chromatography (SiO2 60 F).

後処理

  1. filtrationThe reaction mixture is clarified by filtration
  2. customthe filtrate is evaporated

出典と根拠

ORDレコード
ord-04eaa553a8774abab23d4618f0b453fb
出典データセット
uspto-grants-2011_12
特許番号
US08071651B2

反応ノート

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