Nitric Acid → 5-Chloro-2-methyl-6-nitro-1-indanone

HRID 65938ノート

反応式

HRID 65938 の反応式
[Cl:1][C:2]1[CH:3]=[C:4]2[C:8](=[CH:9][CH:10]=1)[C:7](=[O:11])[CH:6]([CH3:12])[CH2:5]2.[N+:13]([O-])([OH:15])=[O:14]>>[Cl:1][C:2]1[CH:3]=[C:4]2[C:8](=[CH:9][C:10]=1[N+:13]([O-:15])=[O:14])[C:7](=[O:11])[CH:6]([CH3:12])[CH2:5]2

参加物

3

反応物 2

HCID 944Nitric AcidHCID 219956145-Chloro-2-methyl-2,3-dihydro-1H-inden-1-one

生成物 1

HCID 227563825-Chloro-2-methyl-6-nitro-1-indanone

実験手順

According to Example 1 (a), 28.0 g (0.155 mole) of 5-chloro-2-methyl-1-indanone and 180 ml of fuming nitric acid yield the nitro compound having a melting point of from 75° to 78° C., which after recrystallization from ethanol rises to 87° to 89° C.

出典と根拠

ORDレコード
ord-0faa3bdf0f024bf79037ff85cbe5db54
出典データセット
uspto-grants-1978_12
特許番号
US04129656

反応ノート

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