4-Oxobutanoic acid → 1-Piperidinium

HRID 66157

反応式

HRID 66157 の反応式
[O:1]=[CH:2][CH2:3][CH2:4][C:5]([OH:7])=[O:6].[NH:8]1[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1>C1C=CC=CC=1>[NH2+:8]1[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1.[O:1]=[CH:2][CH2:3][CH2:4][C:5]([O-:7])=[O:6]

参加物

5

反応物 2

HCID 11124-Oxobutanoic acidHCID 8082Piperidine

生成物 2

HCID 6379691-PiperidiniumHCID 95432384-Oxobutanoate

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

実験手順

100 Mg. of 4-(8-methoxy-6,11-dihydrodibenzo-[b.e.]-thiepin-11-one-3-yl)-4-oxobutyric acid in 10 ml. of benzene is treated with 60 mg. of piperidine. The solution obtained is allowed to stand for one hour and the crystalline material which forms is filtered, washed with ether and air dried to yield piperidinium 4-(8-methoxy-6,11-dihydrodibenzo-[b.e.]-thiepin-11-one-3-yl)-4-oxobutyrate.

後処理

  1. customThe solution obtained
  2. filtrationthe crystalline material which forms is filtered
  3. washwashed with ether and air
  4. customdried

出典と根拠

ORDレコード
ord-95cdf6991778486985518cab3455bb88
出典データセット
uspto-grants-1978_12
特許番号
US04130654

関連ノート

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