Dimethylformamide dimethyl acetal → Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene

HRID 66219

反応式

HRID 66219 の反応式
[NH:1]1[CH2:12][CH2:11][CH2:10][NH:9][CH2:8][CH2:7][CH2:6][NH:5][CH2:4][CH2:3][CH2:2]1.[CH3:13]OC(OC)N(C)C>>[N:1]12[CH:13]3[N:9]([CH2:8][CH2:7][CH2:6][N:5]3[CH2:4][CH2:3][CH2:2]1)[CH2:10][CH2:11][CH2:12]2

参加物

3

反応物 2

HCID 78373Dimethylformamide dimethyl acetalHCID 4707781,5,9-Triazacyclododecane

生成物 1

HCID 12641659Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene収率 73.1%

実験手順

In a manner similar to that of Example 1 (C), 5.00 g (29.2 mmol) of 1,5,9-triazacyclododecane and 3.48 g of dimethylformamide dimethyl acetal were reacted to give 3.87 g of 1,5,9-triazatricyclo[7.3.1.05,13 ]tridecane as a clear, colorless liquid, bp 93° (three fractions) (0.35 mm), which solidified on standing at room temperature. One fraction was analyzed.

出典と根拠

ORDレコード
ord-d742f01c8a9a451f8198c8a3497b4046
出典データセット
uspto-grants-1978_12
特許番号
US04130715

関連ノート

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