Sodium Hydroxide → Sodium 4-methyl-1-homopiperazinedithiocarboxylate monohydrate

HRID 66300ノート

反応式

HRID 66300 の反応式
[CH3:1][N:2]1[CH2:8][CH2:7][CH2:6][N:5]([C:9]([SH:11])=[S:10])[CH2:4][CH2:3]1.[OH-:12].[Na+:13]>O>[OH2:12].[CH3:1][N:2]1[CH2:8][CH2:7][CH2:6][N:5]([C:9]([S-:11])=[S:10])[CH2:4][CH2:3]1.[Na+:13]

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 1615434-Methyl-1-homopiperazinedithiocarboxylic acid

生成物 1

HCID 23683795Sodium 4-methyl-1-homopiperazinedithiocarboxylate monohydrate収率 54.3%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

57.0 g (0.3 moles) of 4-methyl-1-homopiperazinedithiocarboxylic acid (FLA-57) was dissolved in 300 ml of water with 12.0 g (0.3 moles) of NaOH. The solution was evaporated. The residue was recrystallized from ethanol-isopropyl ether, 37.5 g of sodium 4-methyl-1-homopiperazinedithiocarboxylate monohydrate was obtained. Mp 123°-125° C. elemental analysis. C calculated 36.60%, found 36.5%, H calculated 6.56%, found 6.54%, N calculated 12.16%, found 12.1%, S calculated 27.84%, found 27.8%.

後処理

  1. customThe solution was evaporated
  2. customThe residue was recrystallized from ethanol-isopropyl ether

出典と根拠

ORDレコード
ord-f721086c6d4940a3bc72fb0e2ff26a50
出典データセット
uspto-grants-1978_12
特許番号
US04131671

反応ノート

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