Pentaerythritol → Pentaerythritol Tetrakis(2,4-dimethoxybenzoate)

HRID 66691

反応式

HRID 66691 の反応式
[CH3:1][O:2][C:3]1[CH:11]=[C:10]([O:12][CH3:13])[CH:9]=[CH:8][C:4]=1[C:5](Cl)=[O:6].[OH:14][CH2:15][C:16]([CH2:21][OH:22])([CH2:19][OH:20])[CH2:17][OH:18]>>[CH3:1][O:2][C:3]1[CH:11]=[C:10]([O:12][CH3:13])[CH:9]=[CH:8][C:4]=1[C:5]([O:14][CH2:15][C:16]([CH2:21][O:22][C:5](=[O:6])[C:4]1[CH:8]=[CH:9][C:10]([O:12][CH3:13])=[CH:11][C:3]=1[O:2][CH3:1])([CH2:19][O:20][C:5](=[O:6])[C:4]1[CH:8]=[CH:9][C:10]([O:12][CH3:13])=[CH:11][C:3]=1[O:2][CH3:1])[CH2:17][O:18][C:5](=[O:6])[C:4]1[CH:8]=[CH:9][C:10]([O:12][CH3:13])=[CH:11][C:3]=1[O:2][CH3:1])=[O:6]

参加物

3

反応物 2

HCID 8285PentaerythritolHCID 27347192,4-Dimethoxybenzoyl chloride

生成物 1

HCID 20530744Pentaerythritol Tetrakis(2,4-dimethoxybenzoate)収率 78%

実験手順

Using the procedure of Eample I, 2,4-dimethoxybenzoyl chloride was allowed to react with pentaerythritol in the molar ratio of 4:1. The reaction gave a 78% yield of white crystalline product having a melting point of 125°-126.5° C. and the infrared spectrum was a consistent with the expected tetraester with no hydroxyl band and an ester carbonyl band at 5.85μ (s).

出典と根拠

ORDレコード
ord-42dfaebc9cba4c71a19c8c1f54691fa8
出典データセット
uspto-grants-1982_08
特許番号
US04342875

関連ノート

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